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101.
Proton induced X-ray emission has been used to measureL-subshell and total ionization cross-sections of Au, Pb and Bi in the energy range of 200–350 keV. The ionization cross-sections have been extracted using the X-ray spectra and other quantities like fluorescence yields, transition probabilities, relative widths and Coster-Krönig fraction etc. involved in the process. The results have been compared with the cross-sections measured before and discussed in the light of known theories regarding the ion-atom collisions. 相似文献
102.
Summary Existing thin-layer chromatographic (TLC) methods for the separation of hydroxyanthraquinones in plant materials were found to have limited applications. This initiated the development of some new TLC systems to separate the five principal hydroxyanthraquinones: chrysophanol, physcion, emodin, rhein and aloe emodin normally present together in plant materials, on a single chromatogram and usually with a single solvent system. 相似文献
103.
Choudhary MI Siddiqui ZA Musharraf SG Nawaz SA Atta-Ur-Rahman 《Natural product research》2005,19(4):311-317
The microbial transformation of prednisone (17alpha,21-dihydroxy-pregna-1,4-diene-3,11,20-trione) (1) by Cunninghamella elegans afforded two metabolites, 17alpha,21-dihydroxy-5alpha-pregn-1-ene-3,11,20-trione (2) and 17alpha,20S,21-trihydroxy-5alpha-pregn-1-ene-3,11-dione (3), while the fermentation of 1 with Fusarium lini, Rhizopus stolonifer and Curvularia lunata afforded a metabolite 1,4-pregnadiene-17alpha,20S,21-triol-3,11-dione (4). Compound 3 was found to be a new metabolite. Their structures were elucidated on the basis of spectroscopic techniques. Compound 3 showed inhibitory activity against lipoxygenase enzyme. 相似文献
104.
π-electron SCF-MO theory in its variable electronegativity formalism has been applied to some monosubstituted benzenes. Calculated charge densities and bond orders for the ground and the first excited electronic states are correlated with chemical reactivity and the changes in molecular geometry on electronic excitation. The calculated results for spectra are compared with those obtained using the PPP method and also with the available experimental data. 相似文献
105.
A semi-empirical open shell model of sigma bonded systems has been employed to calculate the binding energies for diatomic lithium halides. The repulsion between the atomic cores is taken as the Coulomb repulsion term modified by the presence of electronic cores. This modification has been estimated from the repulsion term in the Rittner potential function. The agreement with the experimental values is quite satisfactory but the extension of the same method to alkali hydrides results in gross discrepancies. The results are discussed in the light of other results. 相似文献
106.
Phase diagram of durene–resorcinol system, determined by the thaw-melt method, shows the formation of a monotectic (0.109
mole fraction of durene) and an eutectic (0.964 mole fraction of durene) with a large liquid miscibility gap in the region
from 0.109 to 0.964 mole fraction of durene. The eutectic, monotectic and consolute temperatures are 78.4, 107.8 and 165.0°C,
respectively. The growth behaviour studied by measuring the linear velocity of crystallization (v) in a capillary at different undercoolings (ΔT) suggests that the data obey the Hillig–Turnbull equation,v=u(ΔT)n, where u and n are constants depending on the nature of materials involved. From the values of enthalpy of fusion of the pure components,
the eutectic and the monotectic determined by the DSC method using Mettler DSC-4000 system, entropy of fusion, enthalpy of
mixing, Jackson’sroughness parameter, size of the critical nucleus interfacial energy and excess thermodynamic functions were
calculated. The microstructures of the eutectic, and the monotectic, determined by the Leitz Laborlux D optical microscope
show their characteristic features.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
107.
Murtaza G Badshah A Said M Khan H Khan A Khan S Siddiq S Choudhary MI Boudreau J Fontaine FG 《Dalton transactions (Cambridge, England : 2003)》2011,40(36):9202-9211
A series of N,N',N'-trisubstituted guanidines (1-6) and their copper(II) complexes, [κ(2)(O,N)-C(6)H(5)CONHC(NHC(6)H(4)Cl)NR](2)Cu(ii) (R = iso-propyl (1a), n-butyl (2a), sec-butyl (3a), tert-butyl (4a), benzyl (5a), and para-tolyl (6a)) were synthesized and characterized using elemental analysis, FTIR and NMR spectroscopy. DFT studies were used to assess the location of the protons in the free ligands. However, calculations have shown that, in all cases, hydrogen bonding from either N-H group gives conformations that are very similar in energy. Single crystal XRD studies were used to characterize ligands 1 and 4 and the related complexes 1a and 4a. The structures reveal that these complexes are mononuclear in the solid state and that copper adopts a regular square planar geometry. In both metallic species, the N, N', N'-trisubstituted guanidine ligands chelate the Cu(II) atom using the oxygen and one nitrogen. The synthesized compounds were investigated for urease inhibition using thiourea as a standard drug. Most complexes exhibit a better activity than the respective guanidines and compound 1a was found to be the most active with IC(50) = 9.83 ± 0.07 μM (the IC(50) for thiourea is 21.0 ± 0.1 μM). The species were also screened for their anti-leishmanial activity. However, all of the compounds were devoid of any significant activity. 相似文献
108.
Summary The coagulation concentration for silver iodide sol, both in presence of pyridine and dioxane, increases for mono- and bivalent
coagulating electrolyte. In presence of a mixture of pyridine and dioxane in equal volume, the coagulation concentration assumes
an intermediate value, which is nearer to dioxane. However, in presence of dioxane more bivalent electrolyte is needed than
in presence of pyridine. If a bivalent coagulating electrolyte is added to a sol containing a mixture of pyridine and dioxane,
the amount of electrolyte required to coagulate is less than pyridine and greater than dioxane. Thus silver iodide sol is
more stable toward mono- and bivalent coagulating electrolytes. The degree of stabilization increases with the decrease of
the dielectric constant of the dispersing medium. The intermediate values for dioxane pyridine mixture is accountable by the
fact that dioxane acts as a solvent for pyridine. The PH value of the sol increases up to the coagulation point. Beyond this,
there is an abrupt decrease. When the particles settle down completely a rise in PH is again noted on the further addition
of electrolytes. The increase in the electrical conductance is more significant after coagulation. These changes have been
explained by adsorption of the ions and due to the release of ions from the electrical double layer.
Our thanks are due to Prof. R. C. Mehrotra for providing all the facilities for this work and to Prof. S. Ghosh of Allahabad University for helpful discussions. Thanks are also due to the University Grants Commission, Government of India, for the award of a research scholarship to one of us (V. K. S.). 相似文献
Zusammenfassung Die Koagulationskonzentration für Silberjodidsol in Gegenwart von Pyridin und Dioxan steigt für ein- und zweiwertige Elektrolyte an. In Gegenwart einer Mischung zu gleichen Volumen erh?lt man mittlere Werte, n?her denen zu Dioxan. Für Koagulation in Gegenwart von Dioxan ist jedoch mehr zweiwertiger Elektrolyt notwendig als in Gegenwart von Pyridin. Bei Koagulation mit zweiwertigem Elektrolyt verbraucht ein Sol mit der Mischung von Pyridin und Dioxan weniger als für Pyridin und mehr als für Dioxan. Daher ist das Silbersol gegenüber ein- und zweiwertigen Elektrolyten stabiler. Der Grad der Stabilisierung w?chst mit abnehmender Dielektrizit?tskonstante des Dispersionsmediums. Die Zwischenwerte der Dioxan-Pyridin-Mischungen lassen sich verstehen durch die Tatsache, da? Dioxan als L?sungsmittel für Pyridin wirkt. Der PH-Wert des Sols w?chst bis zum Koagulationspunkt, darüberhinaus erfolgt ein steiler Abfall. Wenn die Teilchen vollst?ndig absetzen, ist bei weiterer Zugabe von Elektrolyt ein erneuter Anstieg im PH feststellbar. Der Anstieg der elektrolytischen Leitf?higkeit wird nach der Koagulation ausgepr?gter. Diese ?nderungen lassen sich durch Ionenadsorption und Freiwerden von Ionen aus der elektrischen Doppelschicht erkl?ren.
Our thanks are due to Prof. R. C. Mehrotra for providing all the facilities for this work and to Prof. S. Ghosh of Allahabad University for helpful discussions. Thanks are also due to the University Grants Commission, Government of India, for the award of a research scholarship to one of us (V. K. S.). 相似文献
109.
The solubility of NdPO4(c) was studied at 23±2 °C from both the over and undersaturation directions, with pH ranging from 0 to 9, P concentrations ranging from 0.0003 to 1.00M, and equilibration periods ranging from 6 to 57 days. Equilibrium was reached in <6 days. From the H+, Nd, and P concentrations in equilibrated solutions, the logarithm of the thermodynamic equilibrium constant for the reaction (NdPO4(c) Nd3++PO4
3-) was calculated to be -24.65±0.23 and the value of the Pitzer ion-interaction parameter (2)for Nd3+-H2PO4
- was determined to be -92.9. Predictions based on these thermodynamic quantities were in excellent agreement with the experimental data. 相似文献
110.
Kumar S Rai AK Singh VB Rai SB 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(11-12):2741-2746
The infrared and Raman spectra of glycine molecule has been studied in spectral region 400-4000 cm(-1) in solid form as well as in water. The vibrational frequencies for the fundamental modes of the glycine in neutral and its zwitterionic form have also been calculated using AM1 semiempirical method as well as ab initio method with minimal basis set. The reliability of the minimal basis set and AM1 method with higher basis sets, for IR spectra of the neutral glycine conformers were examined. We find that the 6-21G basis set calculation yields structural parameters, rotational constant and dipole moment of glycine conformers, which are very similar to those obtained from extended basis set calculation as well as experimental values. IR frequencies for glycine conformer I are also calculated in water using SCRF=PCM model and compared with experimental values. A comparison between calculated frequencies for neutral glycine, and its zwitterionic form with observed IR and Raman bands have been made. The total energies for gas phase glycine and its zwitterionic form along with those of hydrated forms were also calculated. It is found from the calculations that in the gas phase neutral glycine is more stable as compared to its zwitterionic form. 相似文献